Infrared spectra and conformation of substituted 3-benzylidene-2,4-pentanediones
✍ Scribed by A. Perjéssy; P. Hrnčiar
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 551 KB
- Volume
- 38
- Category
- Article
- ISSN
- 1386-1425
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📜 SIMILAR VOLUMES
Infrared spectra of all isomers of polymethyl-substituted benzoic acids were recorded in the carbonyl and hydroxyl regions in tetrachloromethane at various concentrations and interpreted in terms of conformation. According to a plot of #(C=O) of the monomeric form vs Hammett substituent constants ',
## Abstract Substituent effects on the ^13^C and ^1^H chemical shifts have been studied for derivatives of 3‐benzylidene‐2, 4‐pentanedione. A significant correlation has been found between chemical shifts of the __Z__ carbonyl group (C‐2) and Hammett constants, while no correlation has been found f