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Conformational studies of 3-aminomethylene-2,4-pentanedione using vibrational and NMR spectra, and ab initio calculations

✍ Scribed by M. Gróf; A. Gatial; V. Milata; N. Prónayová; L. Sümmchen; R. Salzer


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
642 KB
Volume
843
Category
Article
ISSN
0022-2860

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Vibrational spectra, conformations, ab i
✍ Anne Horn; Peter Klaeboe; Claus J. Nielsen; Gamil A. Guirgis 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 352 KB

The infrared spectra of 3-pentyn-2-ol, CH 3 C"CCH(OH)CH 3 , have been recorded as a vapour and liquid at ambient temperature, as a solid at 78 K in the 4000-50 cm À1 range and isolated in an argon matrix at ca. 5 K. Infrared spectra of the solid phase at 78 K were obtained before and after annealing