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Infrared rotational correlation functions of perpendicular bending vibration in compressed gaseous linear molecules

โœ Scribed by G. Levi; M. Chalaye; E. Dayan

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
335 KB
Volume
12
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Rotational correlation functions, correlation times and band moments have been computed from the band shapes of the vgC2H~ and q-N20 bending vibration, in compressed mixtures vlith N2,02, Ar, H2 and He as Perturbing g+es. Results are compxed with our previous work on the parallel vibration ~3 for the same perturbed molecules.

๐Ÿ“œ SIMILAR VOLUMES

Infrared rotational correlation function
Infrared rotational correlation functions and intermolecular mean squared torques of compressed gaseous linear molecules
โœ M. Chalaye; E. Dayan; G. Levi ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 338 KB

Correlation functions, correlation times, band moments and intermolecular mean squared torques have been computed from the ~3 rotation-vibration band shapes in C2H2 and N20 gas mixtures in the pressure range 10 to 100 bars. Results show an increase of the hindering of the rotation in the order: HecH

Band moments and rotational autocorrelat
Band moments and rotational autocorrelation function in infrared for perpendicular transitions of linear molecules
โœ C. Dreyfus; J. Vincent-Geisse ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 263 KB

use of Gordon's theory the second and fourth band moments are computed Some of these rcsuits are also obwmcd by rclatmg rotational autocorrclatlon functions of dlpolar moment for pnrallcl and pcrpcndlculnr transluon\ TheoretIcal and evperlmentnl results arc compared