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Infrared rotational correlation functions and intermolecular mean squared torques of compressed gaseous linear molecules

✍ Scribed by M. Chalaye; E. Dayan; G. Levi

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 338 KB
Volume: 8
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)80057-x

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✦ Synopsis

Correlation functions, correlation times, band moments and intermolecular mean squared torques have been computed from the ~3 rotation-vibration band shapes in C2H2 and N20 gas mixtures in the pressure range 10 to 100 bars. Results show an increase of the hindering of the rotation in the order: HecH2<Arc02cN2<<C02.

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Infrared rotational correlation functions of perpendicular bending vibration in compressed gaseous linear molecules

✍ G. Levi; M. Chalaye; E. Dayan 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 335 KB

Rotational correlation functions, correlation times and band moments have been computed from the band shapes of the vgC2H~ and q-N20 bending vibration, in compressed mixtures vlith N2,02, Ar, H2 and He as Perturbing g+es. Results are compxed with our previous work on the parallel vibration ~3 for th