Infrared rotation-vibration spectra of ethane: The parallel band, 2ν3, of CH3CD3
✍ Scribed by H.M. Heise; A.R.H. Cole
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 861 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0022-2852
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📜 SIMILAR VOLUMES
The ν 5 fundamental (C-C stretching) of CH 3 CD 3 shows a resolved torsional structure, caused by perturbations due mainly to the linear dependence of the torsional potential barrier on the normal coordinate Q 5 . We were able to analyze this structure and to assign vibration-rotation transition wav
The high resolution infrared spectra of 12 CD 3 I and 13 CD 3 I molecules have been measured in the region of the CD 3 deformation bands n 2 and n 5 using a Fourier transform spectrometer. The coupled band system n 2 , n 5 , and 2n 3 has been analyzed by taking into account the Coriolis resonances n
## Abstract The ν~5~ Raman band of CH~3~CD~3~ was photographed with a resolution of about 0.4 cm^−1^ and analysed by an iterative method, in which the peak wavenumbers of the observed and computed contours are compared directly. Precise values for ν~0~ and Δ__B__ were obtained, whereas it only coul