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Infrared matrix isolation evidence for the formation of (η5-cyclopentadienyl)tricarbonyl-molybdenum and -tungsten radicals in carbon monoxide matrices at 12 K

✍ Scribed by Khalil A. Mahmoud; Antony J. Rest; Helmut G. Alt

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 438 KB
Volume: 246
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(83)80205-8

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## Abstract Infrared spectroscopic evidence (CO stretching region) is presented to show that near‐UV irradiation (280 < λ < 350 nm) of Fe(CO)~5~ in lowdensity polyethylene (LDPE), poly(vinyl chloride) (PVC) and polytetrafluoroethylene (PTFE) films at __ca__ 12 K affords the coordimatively unsturat