Photochemistry of (η5-cyclopentadienyl)-tricarbonylmethylchromium in gas matrices and polymer films at 12—298 K: infrared spectroscopic evidence for reversible carbon monoxide ejection and α-H elimination from the methyl group

Photochemistry of iron pentacarbonyl in

Photochemistry of iron pentacarbonyl in poly(vinyl chloride), polytetrafluoroethylene and low-density polyethylene films at 12–298 K: Infrared spectroscopic evidence for the reversible formation of the carbon monoxide loss products iron tetracarbonyl and tricarbonyl, and their reactions with species in the films

✍ Richard H Hooker; Antony J Rest 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 979 KB

## Abstract Infrared spectroscopic evidence (CO stretching region) is presented to show that near‐UV irradiation (280 < λ < 350 nm) of Fe(CO)~5~ in lowdensity polyethylene (LDPE), poly(vinyl chloride) (PVC) and polytetrafluoroethylene (PTFE) films at __ca__ 12 K affords the coordimatively unsturat