Infrared luminescence of excited SiH3Cl molecules generated by SiH4 chlorination
โ Scribed by E.N. Chesnokov; V.N. Panfilov
- Book ID
- 103664919
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 762 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
Excitation energies are calculated for the states arising from excitation of an outer-most valence electron of HzS, PH3 and S& by the use of the one-center expansion SCF MO and the improved virtual orbital approximations. The results are compared with experimental data.
The kinetics of chlorine transfer from CHzC12, CHC13, cc4, and CCI3CN to the triethylsilyl radical was studied in the liquid phase by a competitive method. Br abstraction from 1- bromopentane was used as a reference. The following Arrhenius parameters were determined: 40 f 0.10 1.11 f 0.18 303-343