Infrared identification of the FCS radical in an argon matrix
✍ Scribed by Nico Caspary; Brent E. Wurfel; Anton Thoma; Günter Schallmoser; Vladimir E. Bondybey
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 812 KB
- Volume
- 212
- Category
- Article
- ISSN
- 0009-2614
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By means of the reaction of atomic H or D (produced either in a microwave discharge or on a W filament) with cithcr NO2 or 0, or atomic 0, we have prepared and trapped OH and OD radicals In sohd Ar at 12 K. characterized by their infrared absorption lines at 354820 and 26 I610 m-'. resuectivelv. The
A new ultraviolet band system idcntZed ar em&ion from the theoretically predicted but so far unobserved '@ state of NO trapped in an argon matrix is reported. The energy of the u = 0 level is estimated to be 6.57 -c 0 015 or 6.785 \* 0.015 eV. The intensity distribution yields an internuclear distan