Infrared diode laser spectroscopy of SCl generated by the photolysis of S2Cl2 and SCl2
โ Scribed by Eberhard Tiemann; Hideto Kanamori; Eizi Hirota
- Book ID
- 107802539
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 536 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0022-2852
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๐ SIMILAR VOLUMES
Reactions of CF2 carbene, generated by infrared CO1 laser photolysis of CHClF>, with Br2, Cl2 and Hz were investigated using infrared diode laser spectroscopy. Absolute rate constants at about 550 K for the reactions with Br2 and Cl\* were found to be (2.7+0.9)x10-I5 and (3Sf l.3)x10-'5cm3molecule '
Arrested rekxation infrared chemiluminescence studies of the H + Cl,, SCl2, !5&12, SCQ and SO&l2 reactions have been made. ihe mean fraction of vibrational fi a~ational) enem released to HCl is 0.40(0.10); 0.40(0.13); 0.38(?0.02); 0.33(?0.02) and 036 (20.02) for the series. Only the H + SC12 reactio