Infrared detection in supercritical-fluid chromatography using xenon
β Scribed by Michael A. Healy; Timothy J. Jenkins; Martyn Poliakoff
- Book ID
- 104181948
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 766 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0165-9936
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Supercritical xenon and CO~2~ are compared as solvents by means of solubilities (calculated by means of the PengβRobinson equation of state) and chromatographic behavior for some polynuclear aromatic hydrocarbons; reasons for the apparent superiority of xenon are discussed. The advantag
The combination of capillary supercritical fluid chromatography (SFC) and Fourier transform infrared spectrometry (FTIR) is demonstrated using a low-volume (0.8 pL) flow cell capable of withstanding high pressures. The design of the interface is presented, and its effect on peak shape and detector s