Infrared collision-induced and far-line absorption in dense CO2 atmospheres
β Scribed by R. Wordsworth; F. Forget; V. Eymet
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 582 KB
- Volume
- 210
- Category
- Article
- ISSN
- 0019-1035
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β¦ Synopsis
Collision-induced absorption is of great importance to the overall radiative budget in dense CO 2 -rich atmospheres, but its representation in climate models remains uncertain, mainly due to a lack of accurate experimental and theoretical data. Here we compare several parameterisations of the effect, including a new one that makes use of previously unused measurements in the 1200-1800 cm Γ1 spectral range. We find that a widely used parameterisation strongly overestimates absorption in pure CO 2 atmospheres compared to later results, and propose a new approach that we believe is the most accurate possible given currently available data.
π SIMILAR VOLUMES
The collision-induced rotational band of Cl14 has been measured at 195 K from ~30 to 900 cm-'. These results have been analyzed with a quantum-mechJnin1 lineshape ~~hich sho\\s that this spectrum can be understood on the basis of octupolc-and he\adecapole-induced dipoles. Iiowever, this analysis has