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Infrared collision-induced and far-line absorption in dense CO2 atmospheres

✍ Scribed by R. Wordsworth; F. Forget; V. Eymet


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
582 KB
Volume
210
Category
Article
ISSN
0019-1035

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✦ Synopsis


Collision-induced absorption is of great importance to the overall radiative budget in dense CO 2 -rich atmospheres, but its representation in climate models remains uncertain, mainly due to a lack of accurate experimental and theoretical data. Here we compare several parameterisations of the effect, including a new one that makes use of previously unused measurements in the 1200-1800 cm Γ€1 spectral range. We find that a widely used parameterisation strongly overestimates absorption in pure CO 2 atmospheres compared to later results, and propose a new approach that we believe is the most accurate possible given currently available data.


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The collision-induced rotational band of Cl14 has been measured at 195 K from ~30 to 900 cm-'. These results have been analyzed with a quantum-mechJnin1 lineshape ~~hich sho\\s that this spectrum can be understood on the basis of octupolc-and he\adecapole-induced dipoles. Iiowever, this analysis has