✦ LIBER ✦

The collision-induced far-infrared absorption band of gaseous methane in the region 30–900 cm−1

✍ Scribed by George Birnbaum; Lothar Frommhold; L. Nencini; H. Sutter

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 417 KB
Volume: 100
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87295-9

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✦ Synopsis

The collision-induced rotational band of Cl14 has been measured at 195 K from ~30 to 900 cm-'. These results have been analyzed with a quantum-mechJnin1 lineshape ~~hich sho\s that this spectrum can be understood on the basis of octupolc-and he\adecapole-induced dipoles. Iiowever, this analysis has revealed the role of bound and predissociating dimers in the spectrum.