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Infrared and EPR spectra of F2NO radicals stabilised in solid argon

✍ Scribed by Eugenii Ya. Misochko; Alexander V. Akimov; Ilya U. Goldschleger; Charles A. Wight


Book ID
111730106
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
195 KB
Volume
8
Category
Article
ISSN
0959-9436

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πŸ“œ SIMILAR VOLUMES


Infrared and EPR Spectroscopic Studies o
✍ I.U. Goldschleger; A.V. Akimov; E.Ya. Misochko; C.A. Wight πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 201 KB

2-fluorovinyl radicals were generated in solid argon by solid-state chemical reactions of mobile F atoms with acetylene and its deuterated analogues. Highly resolved EPR spectra of the stabilized radicals CHF&dbond(\*)CH, CDF&dbond(\*)CD, CHF&dbond(\*)CD, and CDF&dbond(\*)CH were obtained for the fi

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Calcium atoms have been reacted with NO and NO2 upon condensation at high dilution in argon at 15 K. Infrared absorptions at 1357 and 455 cm-\* show appropriate isotopic shifts to be due to @I -O)-and Caf -(NO)-viirations in the Ca%O-species. A strong band at 1244 cm-l is due to YJ of NO; in the Ca?