Infrared and EPR spectra of F2NO radicals stabilised in solid argon
β Scribed by Eugenii Ya. Misochko; Alexander V. Akimov; Ilya U. Goldschleger; Charles A. Wight
- Book ID
- 111730106
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 195 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0959-9436
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π SIMILAR VOLUMES
2-fluorovinyl radicals were generated in solid argon by solid-state chemical reactions of mobile F atoms with acetylene and its deuterated analogues. Highly resolved EPR spectra of the stabilized radicals CHF&dbond(\*)CH, CDF&dbond(\*)CD, CHF&dbond(\*)CD, and CDF&dbond(\*)CH were obtained for the fi
Calcium atoms have been reacted with NO and NO2 upon condensation at high dilution in argon at 15 K. Infrared absorptions at 1357 and 455 cm-\* show appropriate isotopic shifts to be due to @I -O)-and Caf -(NO)-viirations in the Ca%O-species. A strong band at 1244 cm-l is due to YJ of NO; in the Ca?