ChemInform Abstract: Solid State Photoch
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M. SAKAMOTO; M. TAKAHASHI; T. ARAI; M. SHIMIZU; K. YAMAGUCHI; T. MINO; S. WATANA
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Article
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2010
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John Wiley and Sons
⚖ 31 KB
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Solid State Photochemical Reaction of Achiral N-(β,γ-Unsaturated Carbonyl)thiocarbamate to Optically Active Thiolactone in the Chiral Crystalline Environment. -The solid-state photoreaction, leading to optically active γ-thiolactone (II), proceeds via intramolecular [2 + 2] thietane formation and s