✦ LIBER ✦
ChemInform Abstract: Solid State Photochemical Reaction of Achiral N-(β,γ-Unsaturated Carbonyl)thiocarbamate to Optically Active Thiolactone in the Chiral Crystalline Environment.
✍ Scribed by M. SAKAMOTO; M. TAKAHASHI; T. ARAI; M. SHIMIZU; K. YAMAGUCHI; T. MINO; S. WATANABE; T. FUJITA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Solid State Photochemical Reaction of Achiral N-(β,γ-Unsaturated Carbonyl)thiocarbamate to Optically Active Thiolactone in the Chiral Crystalline Environment.
-The solid-state photoreaction, leading to optically active γ-thiolactone (II), proceeds via intramolecular [2 + 2] thietane formation and subsequent rearrangement. -(SAKAMOTO,