Tunnel effect on the kinetics of a sigma
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Karl-Heinz Grellmann; Ulrich Schmitt; Horst Weller
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Article
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1982
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Elsevier Science
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English
β 454 KB
Non-hear Anhenius plots and large kmetk tsotope effects observed III slgmatropic hydrogen shifts of photochemlclllly generated tramlent di-and he?ra-hydrocarbuoles are interpreted as tunnel contrlbutlons An Eckti bamer was used to cddate the quantum-mechanrcal transmtssion probabiiticsof the tunnebn