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Influence of the texture of the polymer support on the kinetics of reduction by supported borohydride

✍ Scribed by S. Wali Alami; C. Caze


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
220 KB
Volume
23
Category
Article
ISSN
0014-3057

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✦ Synopsis


The influence of the texture of the polymer support on the kinetics of reduction by supported borohydride is examined. The polymer supports are obtained by chemical modification of styrene/DVB copolymers (chloromethylation and amination). We have shown that the kinetics depend on the texture of the polymeric support. This dependence is explained by the site accessibility which depends on three parameters, viz. surface area, pore volume and crosslinking degree.


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