Space charge trapping has been studied by the thermal step (TS) method for four samples of polypropylene (PP) of di †erent tacticities, prepared by selective extractions from an additive-free commercial polymer with mixtures of a non-polar/polar pair of solvents of various compositions. The experim
Influence of the tacticity dependent microstructure on the space charge distribution of poly(vinyl chloride)
✍ Scribed by Nathalie Vella; Alain Toureille; Nekane Guarrotxena; José-Luis Millan
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 499 KB
- Volume
- 197
- Category
- Article
- ISSN
- 1022-1352
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✦ Synopsis
Abstract
The space charge distribution of three samples of poly(vinyl chloride) of different isotactic content has been studied by the thermal step technique, with a view to investigating the influence of some defined microstructural features on that important behaviour. It has been observed that the space charge increases substantially as the content of the local tetrad configuration, mmr, at the end of isotactic sequences increases. A first tentative interpretation is given.
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