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Influence of the tacticity dependent microstructure on the space charge distribution of poly(vinyl chloride)

✍ Scribed by Nathalie Vella; Alain Toureille; Nekane Guarrotxena; José-Luis Millan


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
499 KB
Volume
197
Category
Article
ISSN
1022-1352

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✦ Synopsis


Abstract

The space charge distribution of three samples of poly(vinyl chloride) of different isotactic content has been studied by the thermal step technique, with a view to investigating the influence of some defined microstructural features on that important behaviour. It has been observed that the space charge increases substantially as the content of the local tetrad configuration, mmr, at the end of isotactic sequences increases. A first tentative interpretation is given.


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