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Influence of the supporting salt concentration on the electrodeposition of ZnO/eosin Y hybrid films

✍ Scribed by Boeckler, C. ;Oekermann, T. ;Saruban, M. ;Ichinose, K. ;Yoshida, T.


Book ID
105364913
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
273 KB
Volume
205
Category
Article
ISSN
0031-8965

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✦ Synopsis


Abstract

ZnO/eosin Y hybrid films were electrodeposited from O~2~‐saturated ZnCl~2~‐solution under variation of the concentration of the supporting salt KCl. The supporting salt concentration was found to have a significant influence on the amount of dye loading and the morphology of the ZnO/eosin Y films. By decreasing the supporting salt concentration to 0.01 M KCl, porous films with a high dye loading can be obtained at potentials of –0.8 V vs. SCE at low eosin Y concentrations in the electrodeposition bath, which usually only lead to porous films at potentials where eosin Y is reduced (< –0.9 V vs. SCE). (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)


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