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Influence of the solvent on the photochemical solvolysis of triarylacetonitriles

โœ Scribed by V. B. Ivanov; V. L. Ivanov; E. M. Kaplan; M. G. Kuz'min


Book ID
112363658
Publisher
Springer
Year
1975
Tongue
English
Weight
311 KB
Volume
9
Category
Article
ISSN
0040-5760

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Nordlander' has recently evaluated expression (i) for a number of solvents, where k pinOTs and kg adOTs are the solvolytic rate constants for pinacolyl tosylate and Z-adamantyl tosylate respectively in those solvents and interpreted the data in terms of ion-pair return in the solvolysis of 2-adamant