Influence of solvent on photochemical isomerization: photophysics of diphenyl butadiene in polar solvents
โ Scribed by Kim M. Keery; Graham R. Fleming
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 409 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The absorption and emission properties of rhodamine 101 in polar, aprotic propionitrile-butyronitrile (45 v/v) solvent have been investigated. The equilibrium between the neutral zwitterionic and lactonic (colourless) forms is strongly affected by the temperature in the range 293-144 K. In dilute so
We study the solvent effects on the isomerization of 1,2-dichloroethane in acetonitrile, chloromethane and carbon tetrachloride by molecular dynamics simulation. The stabilization of the gauche conformer in polar solvents is found to be accompanied by a decrease in the (transition state) isomerizati
The solvent effect on the emission and absorption properties of the ~-naphthoIate anion was studied and the lifetimes measured. In all solvents only a single peah is observed in the spectra. In spite of the lack of resolved spectral bands, the combination of shifts and lifetimes made it possible to