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Influence of the nature and presence of the solvent on H atom abstraction by O2 and electron transfer O2 → O2⨪ during the aerobic oxidation of electronrich Fe(I) sandwiches

✍ Scribed by Jean-René Hamon; Didier Astruc; Pascal Michaud


Book ID
104138689
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
79 KB
Volume
40
Category
Article
ISSN
0020-1693

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The oxidation of Fe(II) at nanomolar levels with O 2 , H 2 O 2 and their mixtures has been studied and a kinetic model has been applied to describe the experimental results. A first order pH dependence is obtained when the H 2 O 2 controls the oxidation, due to the large contributions of FeOH + and