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ChemInform Abstract: Trifluoromethylation of Various Aromatic Compounds by CF3I in the Presence of Fe(II) Compound, H2O2 and Dimethylsulfoxide.

✍ Scribed by Tatsuhito Kino; Yu Nagase; Yuhki Ohtsuka; Kyoko Yamamoto; Daisuke Uraguchi; Kenji Tokushisa; Tetsu Yamakawa


Publisher
John Wiley and Sons
Year
2010
Weight
93 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Chemistry in Supera
✍ G. A. Olah; A. Orlinkov; A. B. Oksizogly; G. K. Surya Prakash πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB πŸ‘ 1 views

3 ) 3 . The reaction proceeds with high regioselectivity. Thus, methanesulfonylation of 1,2,4-trifluorobenzene (V) exclusively affords the 1-mesyl-2,4,5-trifluorobenzene (VI). In dihalobenzenes [cf. compounds (VII) and (Ia)], the para-position is predominantly substituted [cf. compound (VIII)]. Othe