✦ LIBER ✦

Influence of the doped counteranions on the penetration of H+ cations through poly(N-methylpyrrole)

✍ Scribed by Jianyong Ouyang; Yongfang Li

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 418 KB
Volume: 59
Category: Article
ISSN: 0021-8995
DOI: 10.1002/(sici)1097-4628(19960321)59:12<1827::aid-app3>3.0.co;2-s

No coin nor oath required. For personal study only.

✦ Synopsis

The reduction of H+ cations on the Pt electrode coated with poly(N-methylpyrrole) (PNMP) film was studied in an acidic aqueous solution. The reduction depends strongly on the counteranions originally doped in PNMP during polymerization. H+ cations can penetrate the neutral or overoxidized film from PNMP(Ts0-), in which the H+ diffusion coefficient is estimated as cm2 s-l by the potential step chronoamperometry method. But the neutral or overoxidized film from PNMP(N0,) is closed for H+ penetration.

📜 SIMILAR VOLUMES

On the pH Influence on Electrochemical P

On the pH Influence on Electrochemical Properties of Poly(pyrrole) and Poly(N-methylpyrrole)

✍ Agata Michalska; Krzysztof Maksymiuk 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 74 KB 👁 1 views

Synthesis and Crystal Structures of Hydr

Synthesis and Crystal Structures of Hydrogen Monofluorophosphates with N-containing Organic Cations. The Influence of Fluorine on their Hydrogen Bond Systems

✍ H. A. Prescott; S. I. Troyanov; M. Feist; E. Kemnitz 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 176 KB 👁 1 views

The synthesis and crystal structures of guanidinium monofluorophosphate and hydrogen monofluorophosphates with the following cations: piperazinium, di-and triethylammonium, guanidinium, and dimethyluronium, are described and discussed. The structures of the acid salts consist of hydrogen-bonded HPO

Conformation of Polyelectrolyte Chains i

Conformation of Polyelectrolyte Chains in Dilute Aqueous Solutions Investigated by Conductometry, 2. Influence of Temperature, Chain Length and N-Alkyl Substituents on the Conformation of Exhaustively Alkylated Poly(N-alkyl-4-vinylpyridinium) Cations

✍ Olga V. Davydova; Alexander N. Zelikin; Sergei I. Kargov; Vladimir A. Izumrudov 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB 👁 2 views

Conformation of Polyelectrolyte Chains i

Conformation of Polyelectrolyte Chains in Dilute Aqueous Solutions Investigated by Conductometry, 3. Influence of Charge Density on the Conformation of Partly Alkylated Poly(N-ethyl-4-vinylpyridinium) Cations and Ionenes

✍ Olga V. Davydova; Alexander N. Zelikin; Sergei I. Kargov; Vladimir A. Izumrudov 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB 👁 2 views

Temperature dependence of the mean charge spacing b, for PEVP-b samples, DP = 100, with different degrees of alkylation: b = 30 (1), 40 (2), 60 (3), 70 (4), and 95 (5)