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Synthesis and Crystal Structures of Hydrogen Monofluorophosphates with N-containing Organic Cations. The Influence of Fluorine on their Hydrogen Bond Systems

✍ Scribed by H. A. Prescott; S. I. Troyanov; M. Feist; E. Kemnitz


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
176 KB
Volume
628
Category
Article
ISSN
0372-7874

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✦ Synopsis


The synthesis and crystal structures of guanidinium monofluorophosphate and hydrogen monofluorophosphates with the following cations: piperazinium, di-and triethylammonium, guanidinium, and dimethyluronium, are described and discussed. The structures of the acid salts consist of hydrogen-bonded HPO 3 F tetrahedra, which form infinite chains or cyclic dimers. The organic cations link these units together. All of the hydrogen bond systems