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Influence of solvent reorientation dynamics upon the kinetics of some electron-exchange reactions

✍ Scribed by Michael J. Weaver; Thomas Gennett

Book ID
103025552
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
373 KB
Volume
113
Category
Article
ISSN
0009-2614

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✦ Synopsis

The role of solvent reorientation dynamics is explored for outer-sphere electron transfer by examining the solventdependent rates for electrochemical exchange of selected organometallic redox couplesβ€’ The observations are consistent with the anticipated variations in the solvent reorientation frequency. The implications of these findings to other reactions involving only small bond distortions are noted.

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✍ W.Ronald Fawcett; Colby A. Foss Jr πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 900 KB

## Abstrae~lvent effects studied in simple heterogeneous redox reactions, and for amalgam formation reactions have been reviewed. It is emphasized that on the basis of a regression analysis of the data, solvent effects relating to the pm-exponential factor of the electron transfer rate wnstant can