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Influence of simultaneous doping of Sb and Pb on phase formation, superconducting and microstructural characteristics of HgBa2Ca2Cu3O8+δ

✍ Scribed by Rajiv Giri; R.S. Tiwari; O.N. Srivastava


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
851 KB
Volume
451
Category
Article
ISSN
0921-4534

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✦ Synopsis


We report systematic studies of structural, microstructural and transport properties of (Hg 0.80 Sb 0.2Àx Pb x )Ba 2 Ca 2 Cu 3 O 8+d (where x = 0.0, 0.05, 0.1, 0.15, 0.2) compounds. Bulk polycrystalline samples have been prepared by two-step solid-state reaction route at ambient pressure. It has been observed that simultaneous substitution of Sb and Pb at Hg site in oxygen deficient HgO d layer of HgBa 2 Ca 2 -Cu 3 O 8+d cuprate high-T c superconductor leads to the formation of Hg-1223 as the dominant phase. Microstructural investigations of the as grown samples employing scanning electron microscopy reveal single crystal like large grains embodying spiral like features. Superconducting properties particularly transport current density (J ct ) have been found to be sensitive to these microstructural features. As for example (Hg 0.80 Sb 0.05 Pb 0.15 )Ba 2 Ca 2 Cu 3 O 8+d compound which exhibits single crystal like large grains ($50 lm) and appears to result through spiral growth mechanism, shows highest J ct ($1.85 • 10 3 A/cm 2 ) at 77 K. A possible mechanism for the generation of spiral like features and correlation between microstructural features and superconducting properties have been put forward.


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