Influence of polydispersity and long chain branching on the melt viscosity of polycarbonate
β Scribed by Z. Dobkowski
- Book ID
- 107753842
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 560 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0014-3057
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The melt viscosity (,Ta) is calculated for polydisperse branched polymers by two methods: (1) by extending Graessley's theory of melt flow of polydisperse linear chains to include the effects of branching, and (2) by empirical deduction leading to the relation (~TB;'/('/L)= [(Ss:)w/ (SL2)~,] w2 for
Molecular weight distribution and long chain branching were taken into account for the glass transition temperature (Tg)-molecular weight (M) relationships for bisphenol-A polycarbonate. A new form of the four-variable equation for Tg is proposed for polydisperse branched polymers. The extended equa
## Abstract The steadyβstate viscosity Ξ·, the dynamic viscosity Ξ·β², and the storage modulus __G__β² of several highβdensity and lowβdensity polyethylene melts were investigated by using the Instron rheometer and the Weissenberg rheogoniometer. The theoretical relation between the two viscosities as