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Influence of Long-Chain Branching on the Crystallization and Melting Behavior of Polycarbonates in Supercritical CO 2

✍ Scribed by Zhai, Wentao; Yu, Jian; Ma, Weiming; He, Jiasong

Book ID
126087972
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
257 KB
Volume
40
Category
Article
ISSN
0024-9297

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Molecular weight distribution and long chain branching were taken into account for the glass transition temperature (Tg)-molecular weight (M) relationships for bisphenol-A polycarbonate. A new form of the four-variable equation for Tg is proposed for polydisperse branched polymers. The extended equa