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Influence of oxidation products on the rate of decomposition of n-decyl hydroperoxide catalyzed by copper stearate

✍ Scribed by B. G. Bal'kov; I. P. Skibida

Book ID
112433533
Publisher
Springer
Year
1969
Tongue
English
Weight
326 KB
Volume
18
Category
Article
ISSN
1573-9171

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The chromium oxide-catalyzed oxidation of allylic alcohols -RIcH(OH)CR2=CItR 3 -by ROOH (R= t-Bu, PhCMe2) affords generally a mixture of RIcocR2=CItR 3 and RIcH=CR2COR 3. The rate of the reaction and the ratio between the two oxidized compounds both depend on the nature of R. It has been concluded t