A comparative cyclic voltammetric study of hydrogen and deuterium sorption into a thin layer palladium electrode from acidic and basic solution containing cesium cations has been performed. Cesium has been detected in palladium electrodes by neutron activation analysis after hydrogen electrolysis fr
✦ LIBER ✦
Influence of lithium cations on hydrogen and deuterium electrosorption in palladium
✍ Scribed by Andrzej Czerwiński
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 467 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
A comparative study has been performed of hydrogen and deutermm sorpbon mslde a thm layer palladmm electrode from acldlc and basic solutions contammg hthmm cations Lithium presumed to be incorporated m electrode, has an mfluence on the a-to /I-phase. transition only m basic solutions, as a result of more negative potentials values of hydrogen (deutenum) absorption An lsotoplc effect has been observed m basic solutions durmg oxldatlon of absorbed deutenum due to the mteractlon mostly between a phase of absorbed hydrogen and incorporated hthmm
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