A comparative study has been performed of hydrogen and deutermm sorpbon mslde a thm layer palladmm electrode from acldlc and basic solutions contammg hthmm cations Lithium presumed to be incorporated m electrode, has an mfluence on the a-to /I-phase. transition only m basic solutions, as a result of
✦ LIBER ✦
Influence of cesium cations on hydrogen and deuterium electrosorption in palladium
✍ Scribed by Andrzej Czerwiński; Marian Czauderna; Grażyna Maruszczak; Iwona Kiersztyn; Roberto Marassi; Silvia Zamponi
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 578 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
A comparative cyclic voltammetric study of hydrogen and deuterium sorption into a thin layer palladium electrode from acidic and basic solution containing cesium cations has been performed. Cesium has been detected in palladium electrodes by neutron activation analysis after hydrogen electrolysis from 0.1 M CsOH and it has a marked inIIuence on the a-to j-phase transition only in basic solution. The results obtained are compared with those of solutions containing lithium cations [A. Czerwiriski,
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