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Influence of Halide Ion and Lewis Acid in the Demetalation of a Spirolactam Cyclohexadienyl Ruthenium Complex

✍ Scribed by Pigge, F. Christopher; Coniglio, John J.; Rath, Nigam P.


Book ID
127257894
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
157 KB
Volume
24
Category
Article
ISSN
0276-7333

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✍ Pei Nian Liu; Zhong Yuan Zhou; Chak Po Lau 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 403 KB 👁 1 views

## Abstract The perchlorate salt of the dicationic bipy–ruthenium complex __cis__‐[Ru(6,6′‐Cl~2~bipy)~2~(H~2~O)~2~]^2+^ effectively catalyzes addition of β‐diketones to secondary alcohols and styrenes to yield the α‐alkylated β‐diketones. In a catalytic addition reaction of acetylacetone to 1‐pheny