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ChemInform Abstract: The Lewis Acidic Ruthenium Complex Catalyzed Addition of β-Diketones to Alcohols and Styrenes Is in Fact Broensted Acid Catalyzed.

✍ Scribed by Pei Nian Liu; Zhong Yuan Zhou; Chak Po Lau

Publisher
John Wiley and Sons
Year
2008
Weight
46 KB
Volume
39
Category
Article
ISSN
0931-7597

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The Lewis Acidic Ruthenium-Complex-Catal
The Lewis Acidic Ruthenium-Complex-Catalyzed Addition of β-Diketones to Alcohols and Styrenes Is in Fact Brønsted Acid Catalyzed
✍ Pei Nian Liu; Zhong Yuan Zhou; Chak Po Lau 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 403 KB 👁 1 views

## Abstract The perchlorate salt of the dicationic bipy–ruthenium complex __cis__‐[Ru(6,6′‐Cl~2~bipy)~2~(H~2~O)~2~]^2+^ effectively catalyzes addition of β‐diketones to secondary alcohols and styrenes to yield the α‐alkylated β‐diketones. In a catalytic addition reaction of acetylacetone to 1‐pheny