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Influence of H-bond chains in solvents on the solubility of inert substances. A new quantitative approach.

✍ Scribed by P.L. Huyskens; M.C. Haulait-Pirson


Book ID
103593915
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
870 KB
Volume
31
Category
Article
ISSN
0167-7322

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Polyethylene (PE) fdm is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp%(CO)z (Cp%$-CsMes) using supercritical CO, and subsequently saturated with HORe (RF= (CFs)zCH or (CFs)sC). At 200 K, the equilibrium between Cp\*Ir(CO)z and the