Calculations have been made for the work of formation of the two-dimensional nucleus of the metals crystallizing in cubic face-centred and cubic body-centred lattices. It is shown that the crystal orientation of thick deposits depends upon this work. The crystallites of electrodedeposited metal have
Influence of crystal orientation in the structure of electrodeposited copper
β Scribed by J.Bebczuk De Cusminsky
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 728 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
An X-ray diffraction study was made of copper electrodeposited on low index planes of copper single crystals . Three characteristic stages occur during the process : (a) epitaxial growth, (b) twin development, (c) polycrystalline growth .
The deposit thickness, Ah, attained just before polycrystalline growth starts, is hyperbolically related to the cd, high cds giving thinner deposits . For a given cd, Ah is a function of the crystallographic orientation of the base single crystal in the order Ahuul > Ahnool > Ah lllol .
Ah ltt " > Ahltsol > Ahulol
Es wird angenommen Bass diese Reihenfolge in direktem Zusammenhang steht, mit der atomischen Dichte der kristalinen Ebenen and der Stabilitat der verschiedenen kristalinen Ebenen, dumb ihre Arbeitsfunktion gemessen .
Der Mechanismus der Erzeugung der polykristalinen Struktur auf Einkristalle wird besprochen .
π SIMILAR VOLUMES
On the basis of the theory of crystal growth, as developed by Stranskl and Kalshev and by Kaishev and Bhznakov, calculations have been made for the formation work W,,, of the twodimensional nuclei of metals with cubic, hexagonal and tetragonal lattices It 1s suggested that the preferred orlentatlon
The texture of electrodeposited copper coatings has been investigated by X-ray (texture gonimeter) and galvanostatic methods. A dependence is found between the sequence of appearance of orientation axes and cd and temperature. The (111) texture axis appears only at high overvoltages (above O-132 V),
The surface topography of copper deposits, grown from acid copper sulphate solutions on electropolished copper cathodes, varies with the orientation of the original cathode surface. The deposit structures fall into groups which may be related to the atomic configuration of the original cathode surf