From ab initio studies of Zn (NH,):+ complexes ( n = 4-6)) their various minimum energy structures have been identified for the first time. The hexa-ammine-Zn(I1) complexes with the coordination numbers (NE) of 4 to 6 have almost the same enthalpies. But, owing to the entropy effect the complex with
Influence of coordination on NH⋯X− hydrogen bonds. Part 1. [Zn(NH3)4]Br2 and [Zn(NH3)4]I2
✍ Scribed by R Eßmann
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 331 KB
- Volume
- 356
- Category
- Article
- ISSN
- 0022-2860
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