✦ LIBER ✦

Induced contributions in the rayleigh spectra of water: A molecular dynamics simulation

✍ Scribed by R. Frattini; M. Sampoli; M.A. Ricci; G. Ruocco

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 350 KB
Volume: 141
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)85027-3

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✦ Synopsis

A molecular dynamics simulation of TIP4P water at T=280 K has been performed to calculate the depolarized and isotropic Raman spectra in the translational and librational region. Comparison of the isotropic spectra with experiment confirms the assignment of the low-frequency scattered light to collision-induced phenomena and allows identification of the spectral contributions arising from polarizability modulation due to short-range interactions.

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