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Indium Triflate-Catalysed Addition of Thio Compounds to Camphene: A Novel Route to 2,3,3-Trimethyl-2-thiobicyclo[2.2.1]heptane Derivatives

✍ Scribed by Michel Weïwer; Xavier Chaminade; J. Carles Bayón; Elisabet Duñach

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 124 KB
Volume: 2007
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200601112

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✦ Synopsis

Abstract

In^III^ triflate‐catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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