Water as a solvent was found to accelerate the indium-mediated Barbier type allylation and benzylation of b,g-unsaturated piperidinium ion which was generated from b,g-unsaturated a-methoxy-N-methoxycarbonylpiperidine, while ring-opened allylated product was obtained in a case using b,g-saturated a-
Indium-Mediated Nucleophilic Substitution Reaction of β,γ-Unsaturated α-Methoxypiperidine Derivative in Water.
✍ Scribed by Yoshihiro Matsumura; Osamu Onomura; Hideaki Suzuki; Shigeru Furukubo; Toshihide Maki; Chao-Jun Li
- Book ID
- 101950916
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 101 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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Abstract
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