Allylindium reagents, prepared from excess allylic halide (Br or I) and indium metal, react with α,β-unsaturated ketones and aldehydes to give, after aerobic acidic workup, homoallyl-substituted vinylcyclopropanes. This process was explored and developed after a chance discovery arising from a side
✦ LIBER ✦
ChemInform Abstract: Highly Substituted Homoallylvinylcyclopropanes by Indium-Mediated Reaction of α,β-Unsaturated Ketones and Aldehydes with Allylic Halides.
✍ Scribed by Stephen M. Capps; Timothy P. Clarke; Jonathan P. H. Charmant; Henning A. F. Hoeppe; Guy C. Lloyd-Jones; Martin Murray; Torren M. Peakman; Rosie A. Stentiford; Kenneth E. Walsh; Paul A. Worthington
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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