Indirect nuclear spin—spin coupling constants 1J(13C13C) in alkynes
✍ Scribed by Angelika Sebald; Bernd Wrackmeyer
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 362 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1386-1425
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📜 SIMILAR VOLUMES
## Abstract The synthesis of six 1‐X‐ (X = OH, OCH~3~, OCOCH~3~, CH~3~, CHO and CN) phenanthrene derivatives with a ^13^C label at C‐1 is described. An analysis of the ^13^C^13^C spin coupling constants shows the importance of π‐interaction for the coupling constant transmission. Small ^13^C^13^C s
## Abstract A series of 7‐^13^C‐labeled __o__‐substituted toluene derivatives and carboxyl‐^13^C‐isocrotonic and crotonic acid were synthesized and studied by ^13^C NMR spectroscopy to obtain ^13^C^13^C spin‐spin coupling constants involving the labeled carbon. The __cis__ ^3^__J__(CC) values were