Indane-1,2,3-trione ; a highly reactive enophile
β Scribed by G.Bryon Gill; Kirolles S. Kirollos
- Book ID
- 104220615
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 226 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Among the 1,2,3-0ucahbony.l bybtettIb mvebtkgated, udane-1,2,3-throne hub been dound to be a pattacutatty heactlve enoph&c. CLeauagc 05 zthe adductb w&h pe/rLodlc ac&d addokdb a.LLy& Few details are therefore given here. Measurements were made spectrophotometrically; samples were sealed under argon in a silica cuvette, and optical densities monitored at 366nm for & and 553nm for 2. 8. This experiment was performed by Dr. A.R. Shelar.
π SIMILAR VOLUMES
In the title compound, C 30 H 21 NO 3 , the pyrrolidine ring adopts a twist conformation. The dihedral angle between the indan moiety and the phenyl ring is 75.4 (1) . The structure is stabilized by intramolecular CΓHΓ Γ ΓO interactions.