1:1 complex of indan-1,2,3-trione 2-(N-benzoyl-N-phenylhydrazone) with indan-1,2,3-trione 2-(N-phenylhydrazone)
✍ Scribed by McMillan, J. A. ;Curtin, D. Y. ;Paul, I. C.
- Book ID
- 114525432
- Publisher
- International Union of Crystallography
- Year
- 1978
- Weight
- 470 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0567-7408
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Among the 1,2,3-0ucahbony.l bybtettIb mvebtkgated, udane-1,2,3-throne hub been dound to be a pattacutatty heactlve enoph&c. CLeauagc 05 zthe adductb w&h pe/rLodlc ac&d addokdb a.LLy& Few details are therefore given here. Measurements were made spectrophotometrically; samples were sealed under argon
In the title compound, C 30 H 21 NO 3 , the pyrrolidine ring adopts a twist conformation. The dihedral angle between the indan moiety and the phenyl ring is 75.4 (1) . The structure is stabilized by intramolecular CÐHÁ Á ÁO interactions.
In the title compound, C 26 H 27 NO 3 , the pyrrolidine ring adopts an envelope conformation. The indanedione group is planar, the dihedral angle between the fused five-and six-membered rings of this group being 1.1 (2) . There are intramolecular C-HÁ Á ÁO and C-HÁ Á Á interactions.