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Increasing the robustness of heteronuclear decoupling in magic-angle sample spinning solid-state NMR

โœ Scribed by Guillaume Gerbaud; Fabio Ziarelli; Stefano Caldarelli

Book ID
104108337
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
282 KB
Volume
377
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Proton decoupling is a crucial step to obtain high-resolution NMR spectra of macromolecules. Current methods employ phase (or amplitude)-modulated radio-frequency pulses to this end. To be effective, the modulation has to match some resonant condition. We demonstrate in this Communication a simple approach to expand the stability of the resonant condition by convolution of the basic modulation with a Gaussian envelope.

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