✦ LIBER ✦
Improved heteronuclear decoupling schemes for solid-state magic angle spinning NMR by direct spectral optimization
✍ Scribed by Gaël De Paëpe; Paul Hodgkinson; Lyndon Emsley
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 245 KB
- Volume
- 376
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
It is shown that a direct spectral optimization scheme can be implemented to obtain improved heteronuclear dipolar decoupling schemes for solid-state magic-angle-spinning NMR experiments. The resulting schemes, which turn out to have a particularly simple form, are shown to be applicable over the whole range of commercially available spinning speeds (from 5 to 35 kHz), and are shown to improve on the performance of the best existing sequences.