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Incoherent inelastic neutron scattering studies of proton-conducting materials: Sn(HPO4)2·H2O and HM(SO4)2·H2O, M = Fe, In: Part II. The vibrational spectrum of H3O+

✍ Scribed by Deborah J. Jones; Jeffrey Penfold; John Tomkinson; Jacques Rozière


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
358 KB
Volume
197
Category
Article
ISSN
0022-2860

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The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat