The identity of the cation in NH4UO2PO4·3H2O from infrared and inelastic neutron scattering spectroscopies
✍ Scribed by Gordon J. Kearley; Andrew N. Fitch; Brian E.F. Fender
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 339 KB
- Volume
- 160
- Category
- Article
- ISSN
- 0022-2860
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We report the first quasi-elastic neutron scattering analysis of proton mobility in the solid electrolyte CaHPO 4 • 2H 2 O (brushite). We have studied this hydrated phosphate, in powder state, from 190 to 520 K, using an incident wavelength of 5.12 A s . The time of flight spectra are converted in S
4؉ , and As 5؉ , but none of them crystallize in space group Pn2n. In the K/V/P/N(C 2 H 5 ) 3 / H 2 O system, three different K phases were found: K 0.5 VOPO 4 • 1.5H 2 O, KVOPO 4 , and K-FVP-1 (Frankfurt vanadium phosphate, one, or for short, FVP-1). The microporous K-FVP-1 compound was synthesize