In situ SERS study of water molecules on silver electrodes in alkali-hydroxide solutions
β Scribed by T. Itoh; Y. Sasaki; T. Maeda; C. Horie
- Book ID
- 117217674
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 954 KB
- Volume
- 389
- Category
- Article
- ISSN
- 0039-6028
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Hydrogen evolution reaction on AS was investigated in aqueous I M NaOH, UOH, KOH and CsOH solution. A jump was found on the Tafel line in NaOH solution but not in LiOH, KOH and CsOH solutions, even after giving an anodic activation treatment to the electrode . The amount of deposited Na, K and Cs on
Raman spectroscopic evidence is given for the formation of polypyrrole on some silver electrode surfaces. Oxidation of pyrrole and its subsequent polymerisation is merely promoted by the electrode surface illuminated by daylight during oxidation-reduction cycle. For the silver electrode roughened un